Structures published

Journal of the American Chemical Society (2009) 131, 16039-16041

a=10.681(2)Å b=15.350(3)Å c=18.887(4)Å

α=90.00° β=92.59(3)° γ=90.00°

6-KetoDipp-carbene

N_,N{Dipp₂}2,4oxo_3,3{Me₂}

Journal of the American Chemical Society (2009) 131, 16039-16041

a=15.726(3)Å b=9.803(2)Å c=17.111(3)Å

α=90.00° β=90.00° γ=90.00°

6-KetoDipp-Ketene

1,3{Dipp}4,6{Oxo}5{Me₂}2COHMDS

Journal of the American Chemical Society (2009) 131, 16039-16041

a=10.617(2)Å b=11.695(2)Å c=16.402(3)Å

α=82.83(3)° β=87.57(3)° γ=79.23(3)°

6-KetoDipp-Ir(COD)Cl

N_,N(Dipp)_2,4Oxo_3,3(Me₂)₁Ir(COD)Cl

Journal of the American Chemical Society (2009) 131, 16039-16041

a=16.468(3)Å b=19.084(4)Å c=11.224(2)Å

α=90.00° β=90.00° γ=90.00°

DACtBuphenylacetylene

1(4tbutylphenyl)_4,8Mes_26,6dimethyl_4,8diazaspiro[2.5]octane_5,7dione

Journal of the American Chemical Society (2012) 134, 6116-6119

a=16.8334(16)Å b=8.7348(8)Å c=24.305(2)Å

α=90.00° β=100.763(2)° γ=90.00°

DACCyclohexylacetylene

1cyclohexyl_4,8dimesityl_6,6Me_24,8diazaspiro[2.5]oct₁ene_5,7dione

Journal of the American Chemical Society (2012) 134, 6116-6119

a=12.0444(9)Å b=23.2835(17)Å c=11.9648(9)Å

α=90.00° β=103.659(2)° γ=90.00°

DACDMADthermal

dimethyl₂Mes₃(1Mes_5,5dimethyl_4,6dioxo_1,4,5,6tetrahydropyrimidin₂yl)maleate

Journal of the American Chemical Society (2012) 134, 6116-6119

a=20.1337(10)Å b=8.1571(4)Å c=33.9244(17)Å

α=90.00° β=93.899(3)° γ=90.00°

DACMeOBenzonitrile

C₃₂H₃₅N₃O₃

Journal of the American Chemical Society (2012) 134, 6116-6119

a=8.7238(3)Å b=17.0451(7)Å c=18.8797(7)Å

α=90.00° β=95.1970(10)° γ=90.00°

DACDMADKinetic

DACAcetylenedicarboxlicaciddimethylester

Journal of the American Chemical Society (2012) 134, 6116-6119

a=9.2245(14)Å b=11.6531(18)Å c=14.266(2)Å

α=97.528(4)° β=104.301(4)° γ=108.506(3)°

DACTetracyanoethylene

C₃₀H₂₈N₆O₂

Andrew J. Boydston Cory S. Pecinovsky Steven T. Chao Christopher W. Bielawski

Journal of the American Chemical Society (2012) 134, 6116-6119

a=11.880(3)Å b=12.278(3)Å c=12.464(3)Å

α=70.128(5)° β=61.921(4)° γ=73.727(5)°

C₂₂H₂₀N_42,2CH₃SO_41,C₄H₈O

Journal of the American Chemical Society (2007) 129, 14550-14551

a=29.4170(7)Å b=9.9200(3)Å c=20.7890(6)Å

α=90.00° β=115.0970(17)° γ=90.00°

C₅₆H₁₀₄N_42,2BF₄₁

Andrew J. Boydston Cory S. Pecinovsky Steven T. Chao Christopher W. Bielawski

Journal of the American Chemical Society (2007) 129, 14550-14551

a=8.4326(8)Å b=9.5389(11)Å c=19.364(2)Å

α=98.805(6)° β=97.397(8)° γ=99.781(4)°

C₂₀H₂₄N_42,1.4HSO_41,0.6H₄CSO_41,0.4H₂O

Andrew J. Boydston Cory S. Pecinovsky Steven T. Chao Christopher W. Bielawski

Journal of the American Chemical Society (2007) 129, 14550-14551

a=15.6675(9)Å b=8.5227(5)Å c=19.2498(13)Å

α=90.00° β=113.028(3)° γ=90.00°

C₂₉H₂₇ClN₂O₂

Matthew D. Sanderson Justin W. Kamplain Christopher W. Bielawski

Journal of the American Chemical Society (2006) 128, 16514-16515

a=7.9224(2)Å b=16.4652(5)Å c=9.3242(2)Å

α=90.00° β=96.618(2)° γ=90.00°

C₂₉H₂₆N₂O_2,Rh_1,Cl_1,C₈H_12,CHCl₃

Matthew D. Sanderson Justin W. Kamplain Christopher W. Bielawski

Journal of the American Chemical Society (2006) 128, 16514-16515

a=23.6307(2)Å b=9.7837(4)Å c=17.1251(5)Å

α=90.00° β=90.00° γ=90.00°

C₂₉H₂₆N₂O_2,Ag_1,Cl_1,1/2C₄H₈O

Matthew D. Sanderson Justin W. Kamplain Christopher W. Bielawski

Journal of the American Chemical Society (2006) 128, 16514-16515

a=19.1960(7)Å b=19.1960(7)Å c=15.0434(5)Å

α=90.00° β=90.00° γ=90.00°

2C₁₁H₈N_1,C₁₄H₁₁N_21,Ir_3,C₄H₈O

Andrew G. Tennyson Evelyn L. Rosen Mary S. Collins Vincent M. Lynch Christopher W. Bielawski

Inorganic Chemistry (2009) 48, 6924-6933

a=15.7850(8)Å b=9.2310(4)Å c=22.2770(12)Å

α=90.00° β=96.359(2)° γ=90.00°

6KetoMesHoveydaGrubbs2

transCl₂{oiPrbenzylidene}1,3{Mes}5,5Me₂ylidene

Moerdyk, Jonathan P.Bielawski, Christopher W.

Organometallics (2011) 30, 8 2278

a=10.166(2)Å b=11.320(2)Å c=15.196(3)Å

α=75.51(3)° β=84.09(3)° γ=87.83(3)°

7-KetoMes-Ir(cod)Cl

C₃₅H₃₈N₂O₂IrClCH₂Cl₂

Hudnall, Todd W.Tennyson, Andrew G.Bielawski, Christopher W.

Organometallics (2010) 29, 20 4569

a=10.1581(8)Å b=13.4630(10)Å c=13.9170(11)Å

α=111.708(2)° β=91.343(2)° γ=90.782(2)°

DACAcetylene

C₂₆H₃₀N₂O₂

Matthew D. Sanderson Justin W. Kamplain Christopher W. Bielawski

Journal of the American Chemical Society (2012) 134, 6116-6119

a=8.3627(3)Å b=16.4334(6)Å c=15.9457(6)Å

α=90.00° β=99.6680(10)° γ=90.00°

C₂₉H₂₆N₂O₂

Journal of the American Chemical Society (2006) 128, 16514-16515

a=11.9830(10)Å b=13.063(2)Å c=14.646(2)Å

α=90.00° β=90.00° γ=90.00°

C₁₄H₁₂N_2,Ir_,Cl_,C₈H₁₂

Andrew G. Tennyson Evelyn L. Rosen Mary S. Collins Vincent M. Lynch Christopher W. Bielawski

Inorganic Chemistry (2009) 48, 6924-6933

a=7.9260(3)Å b=13.4276(6)Å c=17.6468(10)Å

α=90.00° β=90.648(2)° γ=90.00°

DAC-BH3SMe2 (1SMe2)

C₂₆H₃₇B₁N₂O₂S₁;CH₂Cl₂

Organometallics (2016) 35, 5 706

a=16.852(12)Å b=13.499(10)Å c=12.826(9)Å

α=90° β=90.981(11)° γ=90°

DAC-BH3py (1py)

C₂₉H₃₇B₁N₂O₂;H₂O

Organometallics (2016) 35, 5 706

a=22.574(3)Å b=8.3284(12)Å c=13.943(2)Å

α=90° β=90° γ=90°

DAC-BH3NMe3 (1NMe3)

C₂₇H₄₃B₁N₃O₂

Organometallics (2016) 35, 5 706

a=8.8352(12)Å b=12.6874(17)Å c=12.1513(17)Å

α=90° β=109.329(3)° γ=90°

DAC-BH3ring expanded (2)

C₂₄H₃₁B₁N₂O₂

Organometallics (2016) 35, 5 706

a=11.659(3)Å b=12.699(3)Å c=15.497(4)Å

α=85.322(5)° β=72.721(5)° γ=88.791(5)°

DAC-9BBN (3)

C₃₂H₄₃B₁N₂O₂;C₆H₆

Organometallics (2016) 35, 5 706

a=8.172(5)Å b=16.783(8)Å c=12.130(7)Å

α=90° β=100.44(2)° γ=90°

DAC-bpin (4)

C₃₀H₄₁B₁N₂O₄

Organometallics (2016) 35, 5 706

a=8.119(2)Å b=11.875(3)Å c=14.958(5)Å

α=82.73(2)° β=86.70(3)° γ=82.128(18)°

DAC-bispin (5)

C₃₆H₅₂B₂N₂O₆

Organometallics (2016) 35, 5 706

a=20.295(3)Å b=18.186(2)Å c=19.281(3)Å

α=90° β=90° γ=90°

2DAC-BH3

C₄₈H₅₉B₁N₂O₂;C₆H₆

Organometallics (2016) 35, 5 706

a=16.8362(3)Å b=12.0920(3)Å c=23.6248(4)Å

α=90° β=91.107(2)° γ=90°

DAC-BCl3

C₂₇H₃₁B₁Cl₃N₂O₂

Organometallics (2016) 35, 5 706

a=9.518(4)Å b=10.870(4)Å c=14.271(5)Å

α=102.578(10)° β=108.45(2)° γ=97.337(9)°

DAC-BF3

C₂₄H₂₈B₁F₃N₂O₂